Spectroscopic and Kinetic Analysis of the Oxidation of Unsaturated Alcohols by N-Chloro Saccharin in Micellar Media
DOI:
https://doi.org/10.29070/nqc16011Keywords:
Unsaturated alcohols, N-chloro saccharin, micellar media, spectroscopic analysis, kinetics, surfactantsAbstract
The oxidation of unsaturated alcohols by N-chloro saccharin (NCS) in micellar medium was methodically examined utilising spectroscopic and kinetic methods to elucidate the reaction process and identify the rate-determining phases. The investigation indicated that the reaction kinetics conformed to pseudo-first-order dynamics concerning NCS, illustrating the oxidant's efficacy under regulated settings. Micelles functioned as nanoreactors, greatly accelerating reaction rates by solubilising substrates and concentrating reactants inside the hydrophobic micellar core. The effects of different surfactants, the structural characteristics of the alcohols, and further reaction parameters were analysed, yielding a thorough comprehension of their influence on the reaction's advancement. Moreover, temperature-dependent analyses facilitated the computation of activation energy and thermodynamic parameters, elucidating the energetic characteristics of the oxidation process. This study provides significant insights into the molecular routes of alcohol oxidation in micellar systems, establishing a solid foundation for optimising these processes for commercial applications and synthetic techniques.
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