Investigation of the Thickness of Various Materials and Gauge Ultrasonic Speed
Advancements in Ultrasonic Characterization of Polymer Systems
DOI:
https://doi.org/10.29070/qw016c25Keywords:
ultrasonic measurements, viscoelastic moduli, polymers, ultrasonic dynamic mechanical analysis, rheological methods, polymer systems, UDMA, operating temperatures, ultrasonic transducers, coupling medium, energy transfer mechanism, test material, characterization of polymers, online monitoring, polymer processing, polymer matrix composites, glass transition, melting, crystallization, curing of thermosetting resinsAbstract
Accordingly, ultrasonic measurements have been used by several authors to monitor the evolution of the viscoelastic moduli of polymers as a function of time or temperature and, recently, become a characterization technique of its own right, generally known as ultrasonic dynamic mechanical analysis (UDMA). Often the technique is used in conjunction with rheological methods as a means of providing a better insight into the viscoelastic behavior of polymer systems. As yet UDMA is underutilized primarily because of the low operating temperatures (usually below 100°C) of commercially available ultrasonic transducers, and also due to the requirement of a coupling medium to ensure an efficient energy transfer mechanism between the transducer and the test material. Despite these limitations, this paper shows that the use of ultrasonics is potentially a powerful method for the characterization of polymers, particularly as a tool for online monitoring of events occurring during polymer processing and in the manufacture of polymer matrix composites. The aim of this paper is to review the progress made in recent years, highlighting the potential and reliability of UDMA for monitoring physical transitions in polymers such as glass transition, melting, crystallization, as well as physical changes taking place during curing of thermosetting resins.References
Abraham, R., Jugan, J., Khadar, A., (1996), Theoretical estimation of ultrasonic velocity in ternary mixtures of methyl ethyl ketone and n-nonane with n-alkanols. J. Pure Appl. Ultrason. 18, 114–117.
Acharya, S, R. Paikray & G.C. Mohanty, (2003) Ultrasonic study of binary mixture of DIBK (di-isobutylketone) with polar liquids, Indian Journal of Pure & Applied Physics, 41 855-890.
Acosta J., Arce A., Rodil E. and Ana Soto (2001), Speeds of Sound, Refractive Indices, and the Corresponding Changes of Mixing at 25°C and Atmospheric Pressure for Systems Composed by Ethyl Acetate, Hexane, and Acetone, J. Chem. Eng. Data, Vol.46, pp.1176-1180.
Adgaonkar C.S. and Agnihotri,(1989), Theoretical evaluation of ultrasonic velocity in binary liquid mixtures, Ultrason,27, 248-251.
Adhikhari, A. B., Rahman, I. M., Uddin, M. A., Hasegawa, H., & Majid, M. A. (2009). Volumetric behavior of the binary mixtures of methyl ethyl ketone with n-hexane, cyclohexane, and benzene at T=(303.15, 313.15, and 323.15) K. Journal of Chemical & Engineering Data, 54(3), 1138-1141.
Akhtar, Y., & Ibrahim, S. F. (2011). Ultrasonic and thermodynamic studies of glycine in aqueous electrolytes solutions at 303K. Arabian Journal of Chemistry, 4(4), 487-490.
Ali A. and Nain A.K. (2002) ‘Ultrasonic study of molecular interaction in binary liquid mixtures at 30°C’, Pramana, Vol.58, pp.695-701.
Aswale S S, Aswale S R, Tayade D T and Raghuwanshi P B(2008), Apparent molar compressibility and specific acoustic impedance of alpha-bromo-acetophenones and coumaran-3-ones in ethanol and dioxane solvents, J. Pure. Appl. Ultrason. 30, pp. 62-68
Awwad A., Kanbrur F.I. and Albos E.I., (1984), Excess volumes of (an n-alkanoal + N- formylmorpholine), J. Chem. Thermodyn., 16, 733.
B H Venkatraman, K B R Varma, (2006), Structural and optical properties of (100-X) (Li2B4O7)-X (Sro-Bi2O3-0.7Nb2O5-0.3 V2O5) glasses and nanocrystal composites, Opt. Mater. 28, 1423.
Baccaro, S., Cecilia, A., Cemmi, A., Chen, G., Mihokova, E., & Nikl, M. (2001). Optical characterization under irradiation of Ce3+ (Tb3+)-doped phosphate scintillating glasses. Nucle Sci, IEEE Transac, 48(3), 360-366.
Bachu, R. K., Patwari, M. K., Boodida, S., & Nallani, S. (2008). Volumetric and transport properties of binary liquid mixtures of aliphatic ketones with phenylacetonitrile at T= 308.15 K. Journal of Chemical & Engineering Data,53(10), 2403-2407.