Zinc Oxidethin film as H2S Gas Sensor

H2S is a poisonous & combustible gas generated in sewage treatment plants, coal mines, & the oil & natural gas sectors. It is widely utilised in the chemical industry, research facilities, & as a process gas in manufacturing of heavy water. At these low levels, it is necessary to detect H2S. Low amounts of this gas may be detected by spectral and fluorescence analyses [2, 3], but these sensors are expensive and huge. Semiconductor gas sensors have shown to be a low- cost and practical alternative for monitoring gas species, as have metal oxide sensors based on SnO2, ZnO. Semiconductor gas sensors have shown to be a low- cost & simple solution for monitoring gas species, & sensors based onmetal oxides such as SnO2,ZnO have been reported to detect H2S gas in the ppm range [4,5]. Low-concentration sensors have recently been identified [6,7]. With a large excitation binding energy (60 meV) and a wide band gap (3.4 eV), zinc oxide (ZnO) has received a lot of attention for its electronic and photonic applications like ultraviolet (UV)/blue light-emitting devices, solar cells, piezoelectric devices, acousto- optical devices, and chemical sensors [8] and [9,10]. The development of gas sensors to detect volatile and harmful gases is now crucial due to concerns about environmental pollution and the safety demands of business and daily life. Because of its great electrochemical stability, non-toxicity, doping adaptability, and inexpensive cost, ZnO has been regarded a viable material for gas sensors. Because the detecting properties of a sensor are heavily dependent on form & dimensionality of the sensing material, several ZnO nanostructures have been manufactured & researched during last decade.

EXPERIMENTAL METHODS

Dip coating was used to deposit films on glass substrates (microscope slides). Before deposition, the substrates were washed using newly made chromic acid, followed by a detergent solution & distilled water. The precursor solution was produced in distilled water with a 0.1Mconcentration of high quality zincacetate (Zn (CH3COO)2) and swirled continuously for 1 hour at room temperature. This solution was placed in a beaker, and the pH was kept at 8. Another beaker is filled with hot water at 750oC. The cleaned glass plate was initially submerged for a few seconds in Zinc acetate solution before being immersed in hot water

(100),(101) and (002) planes corresponds to that of ZnO.

The SEM micrograph of ZnO is1shown in figure above which shows flake like structure all over the plane

concentration for pure ZnO nano composites sensitivity gets increased.

The structural, morphological, optical, & gas sensing characteristics of ZnO nanorods were investigated in this work. The ZnO nanorods are created using a simple dip coating process. The nanorods' structural analysis revealed a hexagonal wurtzite structure. For 30k resolution, flower-like bunches are formed, but for 60kresolution, the crystalstructure is rod-likein FESEM findings. The diameter of rod spans from 20nm to 93nm, with a maximum length of 961 nm discovered. The band-gapof ZnO synthesised with zincnitrate as a precursor and sodium hydroxide as a reducing agent was calculated using an absorption spectra. It was discovered to be 3.37 eV. This value is exactly the same as the advertised value. The thick films were made by screen printing & ranged in thickness from 25m to 35m. The nanocry stalline ZnO-based sensor had the best response to H2S gas.

The authors gratefully acknowledge UGC fellowship for financial support, as well as the lab and library facilities provided by the National Physical Laboratory (NPL), New Delhi, and the Nanomaterials & Environmental Sensors Research Laboratory, Department of Physics at the University of Lucknow, Lucknow, for providing laboratory facilities.

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Department of Physics, University of Lucknow, Lucknow 226007