Study of Tetragonal Distorted Complexes of NI(II)

Characterization and Stereochemistry of Tetragonal Distorted Nickel(II) Complexes

Authors

  • Dr. Arbind Kumar Singh

Keywords:

tetragonal distorted complexes, nickel(II) complexes, monometallic complexes, homobimetallic complexes, elemental measurements, molar conductance, magnetic moment, IR spectroscopy, TGA DTA spectroscopy, octahedral stereochemistry, distorted octahedral stereochemistry, Ni(II) centers, coordination sphere, oxo-bridging, phenolate oxygen atoms

Abstract

Monometallic nickel(II) complexes [Ni(H2nsh)(A)2]•nH2O (where A = water (H2O)n=0 (1), (1) pyridine (py), n=2 (2) 2-picoline(2-pic), n=0(3) 3-picoline(3-pic), n=2 (4) and 4-picoline(4-pic), n=0 (5) and homobimetallic nickel(II) complexes [Ni2(nsh)(A)4]•H2O (where A = water (nH2O), n=1(6) pyridine(py), n=4(7) 2- Elemental measurements, molar conductance, magnetic moment, and electrical and IR and TGA DTA spectroscopic experiments have described the complexes. Monometallic complexes (1) to (5) have octahedral stereochemistry, while complexes (6) to (10) have distorted octahedral stereochemistry, where one of the Ni(II) centres is present in the coordination sphere of N2O2 and another Ni(II) centre is bound to it by oxo-bridging by phenolate oxygen atoms.

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Published

2018-06-02

How to Cite

[1]
“Study of Tetragonal Distorted Complexes of NI(II): Characterization and Stereochemistry of Tetragonal Distorted Nickel(II) Complexes”, JASRAE, vol. 15, no. 4, pp. 500–507, Jun. 2018, Accessed: Nov. 22, 2024. [Online]. Available: https://ignited.in/index.php/jasrae/article/view/8260

How to Cite

[1]
“Study of Tetragonal Distorted Complexes of NI(II): Characterization and Stereochemistry of Tetragonal Distorted Nickel(II) Complexes”, JASRAE, vol. 15, no. 4, pp. 500–507, Jun. 2018, Accessed: Nov. 22, 2024. [Online]. Available: https://ignited.in/index.php/jasrae/article/view/8260