Experiment of Kinetics Oxidation of Substituted 3'-4'-Dimethylphenyl by N-chlorosaticarin in Acetic-acid Reaction

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Published: Mar 1, 2025
DOI: https://doi.org/10.29070/3razbr88
Keywords:
Kinetic energy, Oxidation, Dimethylphenyl, NCSA, N-Chlorosaccharin

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Authors

Ranjan Kumar

Research Scholar, Dept. of Chemistry, Magadh University, Bodh Gaya, Bihar

Dr. Ajendra Kumar

Assistant Professor, Dept of Chemistry, S.M.S.G.College Sherghati (Gaya), Bihar

Abstract

The oxidation process of 3'-4'-dimethylphenyl time and butanoic acid using N-chlorosaccharin in an acetic acid medium, with perhydrochloric acid as a catalyst, was investigated. The reaction followed a primary order with respect to [ka], [NCSA], and [H+]. The sole oxidation product identified was 3,4-dimethylbenzoic acid. To regulate the reaction rate involving the acid and its products, saccharin formed as a byproduct was introduced. The dissociation of ionic forces within the reaction site had minimal influence on oxidation speed across various conditions. However, a slight reduction in the dielectric constant led to a moderate increase in reaction rate. Hypochlorous acid (H₂O⁺Cl) was proposed as the primary oxidizing agent. A reaction mechanism was suggested, aligning with experimental observations, and activation parameters were determined for the rate-limiting steps.

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Vol. 22 No. 1 (2025): Journal of Advances in Science and Technology (JAST)

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