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Authors

Sunil L. Garud

Abstract

Strontium iodate, Sr(IO3)2, has been set up by hydrothermal reactions at 170 deg. C. The X-beam single-crystal basic investigation indicated that it crystallizes in another structure type with space bunch P1-bar, a=7.0130(7) A, b=7.0520(8) A, c=13.088(1) A, α=84.12(1) deg., β=84.80(1) deg., γ=63.48(1) deg., Z=4, R1wR2=0.04420.1019 for 2109 watched reflections and 158 parameters. The crystal structure of Sr(IO3)2 comprises of pyramidal IO3-anions and Sr2+ cations, which are then again organized along the a-hub in a 21 proportion to frame a layer-like structure. Infrared spectra further affirmed that the compound contains low symmetric IO3-gatherings.

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