To Study Metallic Gold Catalyst-Enabled Hydrogen Peroxide Synthesis

Authors

  • Bhong Navanath Narayan Research Scholar, OPJS University, Churu, Rajasthan. Author
  • Dr. R.P. Singh Professor, OPJS University, Churu, Rajasthan Author

DOI:

https://doi.org/10.29070/2dst7k68

Keywords:

synthesis, H2O2, Catalysts, temporal analysis, gold-palladium nanoparticles

Abstract

In this study, we look at the potential for directly monitoring gas-phase H2O2 production in a continuous gas flow reactor. To study how atmospheric and supersonic pressures affect the behavior of gas-phase H2O2 produced directly, we built two lab-scale flow reactors on-site.   The results showed that creating H2O2 directly in the gas phase was challenging, and that the stability of the H2O2 was much diminished due to the absence of a solvent.   Results show that organic molecules may be gas-phase oxidized using oxygen and gold-palladium nanoparticles; this much is proven. Synthesis rates high enough in the TAP reactor and the fixed bed gas phase reactor allowed for the identification of H2O2 as a product. This finding opens the door to the prospect of directly manufacturing H2O2 via a gas phase approach.

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References

J. K. Edwards, B. Solsona, E. Ntainjua, A. F. Carley, A. A. Herzing, C. J. Kiely, G. J. Hutchings, Science, 2009, 323, 1037–1041.

E. N. Ntainjua, M. Piccinini, S. J. Freakley, J. C. Pritchard, J. K. Edwards, A. F. Carley, G. J. Hutchings, Green Chem., 2012, 14, 170.

S. J. Freakley, R. J. Lewis, D. J. Morgan, J. K. Edwards, G. J. Hutchings, Catalysis Today, 2015, 248, 10–17.

M. Piccinini, J. K. Edwards, J. A. Moulijn, G. J. Hutchings, Catalysis Science & Technology, 2012, 2, 1908-1913.

N. N. Edwin, J. K. Edwards, A. F. Carley, J. A. Lopez-Sanchez, J. A. Moulijn, A. A. Herzing, C. J. Kiely, G. J. Hutchings, Green Chem., 2008, 10, 1162–1169.

J. K. Edwards, A. Thomas, B. E. Solsona, P. Landon, A. F. Carley, G. J. Hutchings, Catalysis Today, 2007, 122, 397-402.

J. K. Edwards, G. J. Hutchings, Angewandte Chemie International Edition, 2008, 47, 9192–9198.

J. K. Edwards, J. Pritchard, L. Lu, M. Piccinini, G. Shaw, A. F. Carley, D. J. Morgan, C. J. Kiely, G. J. Hutchings, Angew. Chem. Int. Ed., 2014, 53, 1–5.

M. Sankar, Q. He, M. Morad, J. Pritchard, S. J. Freakley, J. K. Edwards, S. H. Taylor, D. J. Morgan, A. F. Carley, D. W. Knight, C. J. Kiely, G. J. Hutchings, ACS Nano, 2012, 6, 6600–6613.

E. Bengtsson, WO Pat., 9732812, 1997.

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Published

2024-03-01